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Preparing For Glufosinate And 2,4-D Applications

Pesticide applications have come a long way since genetic herbicide tolerance came into the picture. It all began with glyphosate tolerance in Roundup Ready soybeans in 1996. In 2017, Roundup Ready Xtend soybeans took over the fields with tolerance to both glyphosate and dicamba.
seed trait stacks over time
Seed trait stacks over time

Unfortunately, over time pesticide resistance also increased in weed populations so seed traits continue to change to add more active ingredients tolerances. To maintain herbicide effectiveness for the current seed traits, many spray tank mixes now contain multiple active ingredients such as glufosinate and 2,4-D. Adjuvants are a valuable tool to optimize these increasingly complicated tank mixes and help them succeed across a wide range of application conditions.

Glufosinate and 2,4-D work with a broad range of seed traits in most commodity crops, so they are often used together in tank mixes or combined with other active ingredients. These complex tank mixes can benefit from the addition of surfactants, water conditioners, and multifunctional adjuvants to enhance weed control and keep applications on target.

Seed trait with herbicide tolerance table
Seed trait with herbicide tolerance table

Glufosinate applications

Glufosinate is a herbicide that has both contact and systemic mode of actions. It works with a broad range of seed traits over many commodity crops. Like many herbicide active ingredients, environmental conditions and tank mix interactions can create challenges for glufosinate.

Challenges with glufosinate applications

Application environment, time of day applied, antagonism, and foaming are a few common hurdles that glufosinate applicators face. Glufosinate uptake is optimized under sunny, warm conditions, but also does better in humid environments and struggles in arid conditions. Also, the differences among in-can surfactants in the various glufosinate formulations on the market can make it challenging to optimize each tank mix for maximum effectiveness.

Optimizing glufosinate uptake requires the right surface tension in spray droplets
Optimizing glufosinate uptake requires the right surface tension in spray droplets

Glufosinate Adjuvant recommendations

Glufosinate requires a high carrier volume (15-20 gallons per acre) to achieve the best spray coverage possible and good wetting. Glufosinate labels typically recommend the use of ammonium sulfate (AMS). As dry AMS is bulky and therefore not always practical, the functionality of dry AMS can be replaced or enhanced with liquid alternatives or adjuvants that help tank mixes provide similar effectiveness with lower rates of AMS. The dry AMS or the alternatives, together with humectants, can help mitigate the reduced effectiveness in arid conditions.

An optimized, high-quality surfactant is needed to balance good leaf coverage with herbicide uptake. If droplet spreading is excessive, the droplets have a greater surface area and evaporate more quickly, potentially reducing herbicide uptake. If droplets are not spread enough, there won’t be sufficient coverage to provide good weed control. An optimized surfactant will balance these two goals and provide good coverage without reducing herbicide uptake. To assure that the spray droplets remain wet long enough on the leaf surface, adding a humectant can also prolong droplet drying time, giving the herbicide more time to get into the target weed.

Glufosinate can react with calcium ions and lose its functionality. Therefore, water conditioners are essential to prevent the interaction of glufosinate with hard water ions.

Glufosinate foams easily, so use a defoamer to optimize the mixing and application process.

Tank mixing glufosinate with other actives like clethodim or 2, 4-D is very common to provide better control over a range of weed species. If an oil-based active ingredient is added as a tank mix partner, a COC or MSO can enhance the effectiveness of the pesticide.

2,4-D Applications

The systemic herbicide 2,4-D is available in multiple formulation types, including amine, ester, and choline versions. The amine and ester versions have been used for broadleaf control historically, but new 2,4-D choline formulations have gained popularity with the Enlist seed trait platform and have lower drift and volatility potential than older formulations.

Challenges with 2,4-D applications

In tank mixes with 2,4-D, ACC-ase inhibitor herbicides are typically used for volunteer corn and grass control. Grass control herbicides can antagonize phenoxy herbicides like 2,4-D. 2,4-D also has been reported to have diminished control of Kochia in regions like the western corn belt, and inconsistent control of other broadleaf weeds in other regions of the USA.

Volunteer corn and weeds in field due to unsuccessful pesticide spray
Volunteer corn and weeds in field due to unsuccessful pesticide spray

2,4-D Adjuvant recommendations

2,4-D control is dependent upon the herbicide reaching the target, and getting into the target weed. Certain formulations of 2,4-D can benefit from drift and deposition aids, and nonionic surfactants can help spray droplets spread and stick to their target weed leaf surfaces. AMS is commonly recommended with 2,4-D tank mixes and can help to condition spray carrier water and improve uptake of tank mix partners like glufosinate, which may be mixed with 2,4-D. Tank mixes of 2,4-D often include grass control herbicides, and these call for the use of MSO or COC adjuvants. The newer formulations of 2,4-D – Enlist One® and Enlist Duo® – have approved adjuvant tank mix partners listed on their website.

Conclusion

As pesticide resistance continues to increase, more active ingredients are being combined into complex tank mixes. In turn, new seed traits are being developed to prepare crops to handle the broader mix of active ingredients. Looking ahead, XtendFlex will be the next soybean seed trait to take center stage showcasing its glufosinate, dicamba, and glyphosate tolerance capabilities. As seed traits and herbicide tank mixes continue to evolve into the future, adjuvants will be an important tool to optimize applications and reduce the onset of herbicide resistance.

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